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General Aspects in Polymer Synthesis

By Reimschuessel, H. K.

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Book Id: WPLBN0000194737
Format Type: PDF eBook
File Size: 0.5 MB
Reproduction Date: 2005

Title: General Aspects in Polymer Synthesis  
Author: Reimschuessel, H. K.
Language: English
Subject: Government publications, United Nations., United Nations. Office for Disarmament Affairs
Collections: Government Library Collection, Disarmament Documents
Publication Date:
Publisher: United Nations- Office for Disarmament Affairs (Unoda)


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Reimschuessel, H. K. (n.d.). General Aspects in Polymer Synthesis. Retrieved from

Government Reference Publication

Excerpt: The term, synthetic polymer denotes a macromolecule that is constructed from sequences of simple structural units, and is usually derived from monomers by a process of polymerization. The structural units may either be all identical or belong to classes of different types. In the former case, the polymer is known as a homopolymer; in the latter, it is called a copolymer. In either case, any process of converting monomers into a polymeric structure will proceed only if certain chemical, thermodynamical, and mechanistic conditions are satisfied. They are (chemical) a functionality of the monomer of two or higher; (thermodynamical) a negative change in the free energy according to AG,,,, = AH -TAS < 0 ; (mechanistic) a potential for activation of the monomer and a high rate of polymerization in comparison to the sum of the rates of all other possible reactions.


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